(Acetylacetonato-κ2 O,O′)(2-bromo-4-chloro-6-{[2-(dimethylamino)ethylimino]methyl}phenolato-κ3 N,N′,O)oxidovanadium(IV)
نویسنده
چکیده
The V(IV) atom in the title complex, [V(C(11)H(13)BrClN(2)O)(C(5)H(7)O(2))O], is six-coordinated by one phenolate O, one imino N and one amino N atom of the tridentate anionic Schiff base ligand, by one oxide O atom, and by two O atoms of an acetyl-acetonate anion, forming a distorted cis-VN(2)O(4) octa-hedral coordination geometry. The deviation of the V atom from the plane defined by the three donor atoms of the Schiff base ligand and one O atom of the acetyl-acetone ligand towards the oxide O atom is 0.256 (2) Å.
منابع مشابه
Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ3 N,N′,O 1)oxidovanadium(V)]
In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N',O-tridendate 2-eth-oxy-6-{[2-(2-hy-droxy-ethyl-amino)-ethyl-imino]-meth-yl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octa-hedral geometry. The bridging O atoms show one short and one long bond to their two attached V(V) at...
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